Larry —
While my colleague is correct and we are not trained in canon law, this situation looks quite doubtful. The Church's principle is that if someone got married and their spouse has not died, before they can marry someone else after a divorce, they need to get an annulment to prove that the previous marriage was not actually valid.
If an annulment is in process and you attempt to marry before it completes, that marriage would not be considered valid (that is, it is not a real marriage in the eyes of God). That's fairly straightforward.
Generally, it is not advisable to attend the wedding of a marriage you know to be invalid (which, in this case, the evidence is strong that it would have been). This would give scandal as it has the appearance of endorsing the action.
It is canonically forbidden to serve as a witness (best man/maid of honor) for such a wedding.
In extreme circumstances — say it was an immediate family member and, not attending, would cause irreparable harm — it might be permissible to attend if your disapproval was made clear.
Eric
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